Crystal structure of μ-2,2'-bipyrimidine-hexacarbonyl-bis(triphenyl-phosphine) dirhenium(I)bis(trifluoromethanesulfonate) acetonitriletetrasolvate, [Re2(C8H6N4)(CO)6(C18H15P)2](F3CSO3)2·4CH3CN
نویسندگان
چکیده
منابع مشابه
Synthesis, Crystal Structure and Antibacterial Evaluation of Di-μ-chlorido-bis({2-[(4-methoxyphenyl)- iminomethyl]pyridine-κ2N,N']Mercury(II)
New coordination polymer of [HgLCl2]n (1) with HgCl2 and Schiff base bidentate ligand (4-methoxyphenyl) pyridine-2yl methyleneamine (L) was prepared and structurally characterized. In the 1D network structure of 1, the mecury (II) ion adopts an HgN2Cl3 distorted square pyramid geometry. In this complex, one of the chlorine acts as bridging ligand connecting two adjacent mercury(II) ions while, ...
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In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2'-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and the dimethylformamide solvate molecule lie on the inter-section of a twofold rotation axis and a m...
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The centrosymmetric title complex, [μ-ethane-1,2-diylbis(di-phenyl-phosphane)-κ2P:P']bis-[penta-carbonyl-tungsten(0)], [W2(C26H24P2)(CO)10], consists of two W(CO)5 moieties bridged by a bis-(di-phenyl-phosphan-yl)ethane (dppe) ligand. The W0 atom has a slightly distorted octa-hedral coordination environment consisting of 5 carbonyl ligands and one P atom from the bridging dppe ligand with the n...
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The mixed-valence μ-oxide Sn12 cluster, deca-carbonyl-tetra-μ4-oxido-hexa-μ3-oxido-tetra-kis-[μ-2,2'-(pyridine-2,6-di-yl)bis(1,1-di-phenyl-ethano-lato)]deca-tin(II)ditin(IV)dimolyb-denum(O)(2 Mo-Sn) toluene hepta-solvate, [Mo2Sn12(C33H27NO2)4O10(CO)10]·7C7H8, has a crystallographically imposed inversion centre. The asymmetric unit also contains three and a half toluene solvent mol-ecules, one o...
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Di-μ-thio-cyanato-bis-[diamminesilver(I)], [Ag2(μ-SCN)2(NH3)4], was synthesized by the reaction of AgSCN with anhydrous liquid ammonia. In the binuclear mol-ecule, the Ag(I) atom is coordinated by two ammine ligands and the S atom of one thio-cyanate ligand. Two of these [Ag(SCN)(NH3)2] units are bridged by the S atoms of the thio-cyanate anions at longer distances, leading to a dimer with poin...
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ژورنال
عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures
سال: 2005
ISSN: 2197-4578,1433-7266
DOI: 10.1524/ncrs.2005.220.14.110